6´-Aminocinchonidine (CAS-No. 2143936-34-7) is a new member of the Cinchona Alkaloid family. The additional primary...
Buchler Glossary
Wolff Rearrangement
The Wolff Rearrangement allows the generation of ketenes from α-diazoketones. During this reaction an α-diazocarbonyl compound is converted into a ketene by loss of dinitrogen with accompanying 1,2-rearrangement.
Wolff Rearrangement examples catalyzed by cinchona alkaloid derivatives can be found in our free of charge Chiral Catalyst Search.
Example from Literature
Evolution of a Strategy for the Enantioselective Total Synthesis of (+)-Psiguadial B. (Chapman et al.; J. Org. Chem. 2018, 83, 11, 6066-6085.)
Further Articles:
6´-Aminodihydrocinchonidine (CAS-No. 107781-90-8)
6´-Aminodihydrocinchonidine Base (CAS-No. 107781-90-8) is a cinchona alkaloid closely related to 6´-Aminocinchonidine....
6´-Aminodihydrocinchonine (CAS-No. 911708-35-5)
6´-Aminodihydrocinchonine Base (CAS-No. 911708-35-5) is a cinchona alkaloid closely related to 6´-Aminocinchonine....
Alkynylation
Alkynylation is an addition reaction in organic synthesis where a terminal alkyne adds to a carbonyl group to form an...
Allylsilylations
Allylsilylations are performed between allylsilanes and aldehydes furnishes homo allyl alcohols. Using Cinchona...
Aminohydroxylation
The Sharpless Aminohydroxylation allows the syn-selective preparation of 1,2-amino alcohols by reaction of alkenes...