Reactions - Buchler GmbH

Aza-Friedel-Crafts Alkylation, acenaphthenequinoneimines, naphthols, hemiketals, 3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione, Quinine Derivative

Aza-Friedel-Crafts, Friedel-Crafts

Cyclization, substituted (E)-4-(5H-pyrrolo[3,2-d]pyrimidin-7-yl)but-3-en-1-amine, N-iodosuccinimide, 2-heteroaryl pyrrolidines, 1,4-Bis(9-O-dihydroquinidinyl)phthalazine, Dihydroquinidine Derivative

Cyclization, Cyclization, Further Cyclizations, Iodination

Michael Addition, 3‑aryloxindoles, ethenesulfonyl fluoride, substituted 2-(2-oxoindolin-3-yl)ethane-1-sulfonyl fluoride, 1,4-Bis[(9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-9,10-anthracenedione, Dihydroquinidine Derivative

Michael, Michael Addition

Allylic Alkylation, 3-substituted benzofuran-2(3H)-ones, morita–baylis–hillman carbonates, substituted 2-((2-oxo-2,3-dihydrobenzofuran-3-yl)(phenyl)methyl)acrylate, 1,4-Bis[(9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-9,10-anthracenedione, Dihydroquinidine Derivative

Alkylation, Allylic Alkylation

Fluorination, sulfoxonium ylides, selectfluor, benzyltributylammonium chloride, substituted 2-chloro-2-fluoro-1-phenylpropan-1-one, (9S)-(9′′S)-9,9′′-[1,4-phthalazinediylbis(oxy)]bis[6′-methoxy-cinchonan, Quinidine Derivative

alpha-Fluorination, Chlorination, Fluorination

Aldol reaction, aldehydes, α-isocyanoacetates, substituted 4,5-dihydrooxazole-4-carboxylate, silver oxide, 2-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N-[(9S)-6′-methoxycinchonan-9-yl]-benzamide, Quinidine Derivative

Aldol, Aldol, Cyclization, Cyclization, Further Cyclizations

Aldol reaction, TMS-protected 2-(prop-2-yn-1-yl)cyclopentane-1,3-dione, (E)-pent-3-en-2-one, bicylce, N-[(1S,2S)-2-aminocyclohexyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]-thiourea, Quinidine Derivative

Aldol, Hajos–Parrish–Eder–Sauer–Wiechert reaction

Aldol reaction, 3-oxocarboxylic acids, α-ketophosphonates, tertiary α-hydroxyphosphonates, N-[3,5-bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]-urea, Quinidine Derivative

Hydrogenation, α-halogenated ketones, hydrogen, 2-halogen alcohols, iridium catalyst, (9R)-N-[[2-(diphenylphosphino)phenyl]methyl]-6′-methoxy-cinchonan-9-amine, Quinidine Derivative

Hydrogenation, Hydrogenation of ketones

Diels-Alder, phenyl(o-tolyl)methanone, maleimides, tricyclic compound, N-[(1R)-1,2-dimethylpropyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]-thiourea, Quinidine Derivative

Cycloaddition, Diels-Alder reaction

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