6´-Aminocinchonidine (CAS-No. 2143936-34-7) is a new member of the Cinchona Alkaloid family. The additional primary...
Buchler Glossary
Bargellini reaction
The original Bargellini reaction (1906) was a mixture of the reagents phenol, chloroform, and acetone in the presence of a sodium hydroxide solution. Later, organic chemists have used the reaction as a general method of organic synthesis for highly hindered or bulky morpholinones or piperazinones from ketones (particularly acetone) and either β-amino alcohols or diamines. Bargellini reactions have found a widespread use in synthesis.
Several examples of Bargellini reactions promoted by Cinchona Alkaloids can be found in our Buchler Chiral Catalyst Search.
Further Articles:
6´-Aminodihydrocinchonidine (CAS-No. 107781-90-8)
6´-Aminodihydrocinchonidine Base (CAS-No. 107781-90-8) is a cinchona alkaloid closely related to 6´-Aminocinchonidine....
6´-Aminodihydrocinchonine (CAS-No. 911708-35-5)
6´-Aminodihydrocinchonine Base (CAS-No. 911708-35-5) is a cinchona alkaloid closely related to 6´-Aminocinchonine....
Alkynylation
Alkynylation is an addition reaction in organic synthesis where a terminal alkyne adds to a carbonyl group to form an...
Allylsilylations
Allylsilylations are performed between allylsilanes and aldehydes furnishes homo allyl alcohols. Using Cinchona...
Aminohydroxylation
The Sharpless Aminohydroxylation allows the syn-selective preparation of 1,2-amino alcohols by reaction of alkenes...