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Dynamic kinetic resolution, 4-isobutyl-2-(4-(trifluoromethyl)phenyl)oxazol-5(4H)-one, (4-(tert-butyl)phenyl)methanethiol, S-(4-(tert-butyl)benzyl) (R)-4-methyl-2-(4-(trifluoromethyl)benzamido)pentanethioate, (8α,9R)-10,11-Dihydro-6′-methoxy-8′-[(1E)-2-phenyldiazenyl]cinchonan-5′,9-diol, Dihydroquinine Derivative

Dynamic Kinetic Resolution, Resolution

Mannich reaction, (E)-P,P-diphenyl-N-(1-phenylethylidene)phosphinic amide, tert-butyl 2-cyanopropanoate, tert-butyl (4S,5R)-4,5-dimethyl-4-phenyl-4,5-dihydro-1H-imidazole-5-carboxylate, N-[(8α,9S)-10,11-dihydro-6′-methoxycinchonan -9-yl]-2-(diphenylphosphino)-benzamide, Dihydroquinine Derivative

Mannich, Mannich

[3+2]-Cycloaddition, aurone analogues, isocyanoacetates, spiro-1-pyrrolines, N-[(8α,9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-2-(diphenylphosphino)-benzamide, Dihydroquinine Derivative

[3+2]-Cycloaddition, Cycloaddition

Hydrophosphonylation, α,β-unsaturated ketones, diphenyl phosphonate, α-hydroxy phosphonates, 2-[[[[3,5-bis(1,1-dimethylethyl)phenyl]methyl]amino][[(8α,9S)-10,11-dihydro-6′-methoxy-cinchonan-9-yl]amino]methylene]-Propanedinitrile, Dihydroquinine Derivative

Hydrophosphonylation

Hydrophosphonylation, 4-formylbenzonitrile, diphenyl phosphonate, diphenyl (S)-((4-cyanophenyl)(hydroxy)methyl)phosphonate, 2-[[[[3,5-bis(1,1-dimethylethyl)phenyl]methyl]amino][[(8α,9S)-10,11-dihydro-6′-methoxy-cinchonan-9-yl]amino]methylene]-Propanedinitrile, Dihydroquinine Derivative

Hydrophosphonylation

Conia-ene reaction, methyl 2-benzoylhept-6-ynoate, methyl (R)-1-benzoyl-2-methylenecyclopentane-1-carboxylate, N-[3,5-Bis(trifluoromethyl)phenyl]-N′-(8α,9S)-cinchonan-9-ylurea, Cinchonidine Derivative

Conia-ene reaction, Further reactions

Spirocyclization, isatin, malononitrile, ethyl acetoacetate, ethyl (S)-2′-amino-3′-cyano-6′-methyl-2-oxospiro[indoline-3,4′-pyran]-5′-carboxylate, N-[3,5-Bis(trifluoromethyl)phenyl]-N′-(8α,9S)-cinchonan-9-ylthiourea, Cinchonidine Derivative

Spirocyclization

Decarboxylative Protonation, 2-acetamido-2-benzyl-3-ethoxy-3-oxopropanoic acid, ethyl acetyl-D-phenylalaninate, N-(8α,9S)-Cinchonan-9-ylbenzenecarbothioamide, Cinchonidine Derivative

Decarboxylative Protonation, Protonation

Hydrosilylation, (S,E)-1-(3-(benzyloxy)phenyl)-N-(1-phenylethyl)ethan-1-imine, trichlorosilane, (S)-1-(3-(benzyloxy)phenyl)-N-((S)-1-phenylethyl)ethan-1-amine, (8α,9S)-1-(phenylmethyl)-9-[(2-pyridinylcarbonyl)amino]-Cinchonanium bromide, Cinchonidine Derivative

Hydrogenation, Hydrogenation of imines, Hydrosilylation

Isomerization of imines, trifluoromethyl imines, alkyl trifluoromethylated amines, (8α,9R)-2′-Chloro-10,11-dihydro-6′-methoxycinchonan-9-ol, Dihydroquinine Derivative

Isomerization

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