C-5′-Substituted Cinchona Alkaloid Derivatives Catalyse the First Highly Enantioselective Dynamic Kinetic Resolutions of Azlactones by Thiolysis.

DOI Number:

10.1002/ejoc.201300451

Reaction Category:

Educt:

4-isobutyl-2-(4-(trifluoromethyl)phenyl)oxazol-5(4H)-one, (4-(tert-butyl)phenyl)methanethiol

Product:

S-(4-(tert-butyl)benzyl) (R)-4-methyl-2-(4-(trifluoromethyl)benzamido)pentanethioate

Catalyst:

(8α,9R)-10,11-Dihydro-6′-methoxy-8′-[(1E)-2-phenyldiazenyl]cinchonan-5′,9-diol

Cas No:

1508269-31-5

Cas No:

522-66-7