A Bifunctional β‐Isocupreidine Derivative as Catalyst for the Enantioselective Morita–Baylis–Hillman Reaction and a Mechanistic Rationale for Enantioselectivity.

DOI Number:

10.1002/ejoc.201200405

Reaction Category:

RXNO ID:

RXNO_0000076

Educt:

benzaldehyde, 1,1,1,3,3,3-hexafluoropropan-2-yl acrylate

Product:

1,1,1,3,3,3-hexafluoropropan-2-yl (R)-2-(hydroxy(phenyl)methyl)acrylate

Catalyst:

(3α,9S)-3,9-epoxy-10,11-dihydro-6′-[N-(2,2,2-trichloroacetyl)carbamate] cinchonan-6′-ol

Cas No:

1403618-98-3

Cas No:

73522-75-5