Cinchona Alkaloid-Catalyzed Enantioselective Monofluoromethylation Reaction Based on Fluorobis(phenylsulfonyl)methane Chemistry Combined with a Mannich-type Reaction.

DOI Number:

10.1021/ja071509y

Reaction Category:

Educt:

N-Boc α-phenylsulfonyl amines, (fluoromethylenedisulfonyl)dibenzene

Product:

N-Boc α-fluorobisphenylsulfonyl amines

Catalyst:

9-hydroxy-6′-methoxy-1-(phenylmethyl)-(9S)-Cinchonanium chloride (1:1)

Cas No:

77481-82-4

Cas No:

56-54-2