Mechanism and conditions for highly enantioselective epoxidation of α, β-enones using charge-accelerated catalysis by a rigid quaternary ammonium salt.
DOI Number:
10.1021/ol990964z
Reaction Category:
MOP ID:
MOP_0000671
Educt:
(E)-1-(4-fluorophenyl)-3-phenylprop-2-en-1-one
Product:
(4-fluorophenyl)((2S,3R)-3-phenyloxiran-2-yl)methanone
Catalyst:
(8α,9R)-1-(9-anthracenylmethyl)-9- (2-propenyloxy)-Cinchonanium bromide
Cas No:
200132-54-3
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2