Mechanism and conditions for highly enantioselective epoxidation of α, β-enones using charge-accelerated catalysis by a rigid quaternary ammonium salt.

DOI Number:

10.1021/ol990964z

Reaction Category:

Educt:

(E)-1-(4-fluorophenyl)-3-phenylprop-2-en-1-one

Product:

(4-fluorophenyl)((2S,3R)-3-phenyloxiran-2-yl)methanone

Catalyst:

(8α,9R)-1-(9-anthracenylmethyl)-9- (2-propenyloxy)-Cinchonanium bromide

Cas No:

200132-54-3

Cas No:

485-71-2