Desymmetrization of Diolefinic Diols by Enantioselective Amino‐thiocarbamate‐Catalyzed Bromoetherification: Synthesis of Chiral Spirocycles.
DOI Number:
10.1002/anie.201310136
Reaction Category:
MOP ID:
MOP_0000561
Educt:
diolefinic diols, N-bromophthalimide
Product:
substituted ((3R,5S)-3-allyl-5-(bromomethyl)-tetrahydrofuran-3-yl)methanol
Catalyst:
(9S)-9-[N-(4-ethoxyphenyl)carbamothioate]-6′-butoxy-cinchonan-9-ol
Cas No:
1643718-73-3
Associated Product from Buchler GmbH:
Cupreidine Base
Cas No:
70877-75-7