Cation-Controlled Enantioselective and Diastereoselective Synthesis of Indolines: An Autoinductive Phase-Transfer Initiated 5-endo-trig Process.

DOI Number:

10.1021/jacs.5b08834
Link to literature

Reaction Category:

Cyclization | Further Cyclizations | Intramolecular cyclization

MOP ID:

MOP_0000561

Educt:

isopropyl (E)-2-(2-(benzylideneamino)phenyl)-2-phenylacetate

Product:

isopropyl (2R,3R)-2,3-diphenylindoline-3-carboxylate, isopropyl (2R,3S)-2,3-diphenylindoline-3-carboxylate

Catalyst:

(8α,9R)-9-hydroxy-1-(phenylmethyl)-Cinchonanium chloride

Cas No:

69257-04-1

Associated Product from Buchler GmbH:

N-Benzylcinchonidinium Chloride

Cas No:

69257-04-1