Organocatalytic Asymmetric Dearomatization of 3-Nitroindoles and 3-Nitrobenzothiophenes via Thiol-Triggered Diastereo- and Enantioselective Double Michael Addition Reaction.

DOI Number:

10.1021/acs.orglett.9b01688

Reaction Category:

Educt:

4-mercapto-2-butenoate, 3-nitrobenzothiophenes

Product:

tetrahydrothiophenebenzothiophenes

Catalyst:

(αS)-α-[[[[3,5-bis(trifluoromethyl)phenyl]amino]thioxomethyl]amino]-N-(8α,9S)-cinchonan-9-yl-benzenepropanamide

Cas No:

1258793-27-9

Cas No:

485-71-2