Highly enantioselective phase transfer catalyzed alkylation of a 3-oxygenated propionic ester equivalent; applications and mechanism.

DOI Number:

10.1021/ja9835739

Reaction Category:

Educt:

tert-butyl 4,4-bis(4-(dimethylamino)phenyl)but-3-enoate, allylbromide

Product:

tert-butyl (R)-2-(2,2-bis(4-(dimethylamino)phenyl)vinyl)pent-4-enoate

Catalyst:

(8α,9R)-1-(9-anthracenylmethyl)-9- (2-propenyloxy)-Cinchonanium bromide

Cas No:

200132-54-3

Cas No:

485-71-2