Chiral phosphine-free Pd-mediated asymmetric allylation of prochiral enolate with a chiral phase-transfer catalyst.

DOI Number:

10.1021/ol016567h

Reaction Category:

MOP ID:

MOP_0000369

Educt:

tert-butyl 2-((diphenylmethylene)amino)acetate, trans-substituted allyl acetate

Product:

trans-substituted tert-butyl (S)-2-((diphenylmethylene)amino)pent-4-enoate

Catalyst:

triphenyl phosphite, di-μ-chlorobis(η3-2-propenyl)di-palladium, 1-(9-anthracenylmethyl)-9-methoxy-(1S,9R)-cinchonanium iodide

Cas No:

374562-79-5

Cas No:

485-71-2