Organocatalytic enantioselective nucleophilic vinylic substitution by α-substituted-α-cyanoacetates under phase-transfer conditions.
DOI Number:
10.1021/jo070024p
Reaction Category:
MOP ID:
MOP_0000369
Educt:
substituted (Z)-4-chlorobut-3-en-2-one, alpha-substituted-alpha-cyanoacetates
Product:
substituted tert-butyl (R,Z)-2-cyano-5-oxohex-3-enoate
Catalyst:
(9S)-(9′′S)-1,1′′-[1,3-phenylenebis(methylene)]bis[10,11-dihydro-9-(2-propen-1-yloxy)-cinchonanium dibromide
Cas No:
936484-54-7
Associated Product from Buchler GmbH:
Dihydrocinchonine Base
Cas No:
485-65-4