Procedure-Controlled Enantioselectivity Switch in Organocatalytic 2-Oxazolidinone Synthesis.

DOI Number:

10.1021/ja407027e
Link to literature

Reaction Category:

[3+2]-Cycloaddition | Cyclization | Cycloaddition

MOP ID:

MOP_0000715

Educt:

(E)-4-hydroxy-1-(naphthalen-2-yl)but-2-en-1-one, p-Toluenesulfonyl isocyanate

Product:

(R)-4-(2-(naphthalen-2-yl)-2-oxoethyl)-3-tosyloxazolidin-2-one

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-(8α,9S)-cinchonan-9-ylthiourea

Cas No:

890044-38-9

Associated Product from Buchler GmbH:

Cinchonidine Base

Cas No:

485-71-2