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Desymmetrization, symmetrical substituted 2,6-dioxoheptanedioate, 5-substituted cyclohexane-1,3-dione, decalin derivatives, (9S)-10,11-Dihydro-6′-methoxy-9-(9-phenanthrenyloxy)cinchonan, Dihydroquinidine Derivative

Desymmetrization

α-Benzoyloxylation, cyclohexanones, benzoyl peroxide, substituted (R)-2-oxocyclohexyl benzoate, (9R)-10,11-Dihydro-6′-methoxycinchonan-9-amine, Dihydroquinidine Derivative

Further reactions, α-Benzoyloxylation

Cyclization, substituted 2-formylacrylonitrile, cyclohexanone, substituted (4aS,8aR)-8a-hydroxy-4a,5,6,7,8,8a-hexahydro-4H-chromene-3-carbonitrile, (9R)-10,11-Dihydro-6′-methoxycinchonan-9-amine, Dihydroquinidine Derivative

[4+2]-Cycloaddition, Cyclization

Aldol reaction, methyl 2-isocyano-2-phenylacetate, 3-fluorobenzaldehyde, methyl (4R,5R)-5-(3-fluorophenyl)-4-phenyl-4,5-dihydrooxazole-4-carboxylate, silver(I) oxide, N-[(9R)-10,11-dihydrocinchonan-9-yl]-2-(diphenylphosphino)-benzamide, Dihydroquinidine Derivative

Aldol, Aldol

Nucleophilic Addition, substituted methyl 2-(fluoromethyl)acrylate, N‐heterocycles, substituted methyl 2-((1H-pyrrol-1-yl)methyl)acrylate, 1,4-Bis(9-O-dihydroquinidinyl)phthalazine, Dihydroquinidine Derivative

Allylic Amination, Amination

Cyclopropanation, ethyl 2-(6-chloro-9H-purin-9-yl)acrylate, tert-butyl 2-bromoacetate, 2-(tert-butyl) 1-ethyl (1S,2R)-1-(6-chloro-9H-purin-9-yl)cyclopropane-1,2-dicarboxylate, 1,4-Bis[(9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-9,10-anthracenedione, Dihydroquinidine Derivative

Cyclopropanation

Aldol reaction, β-ketoacids, trifluoromethyl ketones, (R)-4,4,4-trifluoro-3-hydroxy-1,3-diphenylbutan-1-one, 1,4-Bis[(9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-9,10-anthracenedione, Dihydroquinidine Derivative

Aldol, Aldol

α-Amination, oxindoles, diethyl (E)-diazene-1,2-dicarboxylate, 3-amino-2-oxindole derivatives, 1,4-Bis(9-O-dihydroquinidinyl)phthalazine, Dihydroquinidine Derivative

alpha-Amination, Amination

Spirocyclization, 2-oxocyclyclic-carbaldehydes, (E)-substituted 2-oxobut-3-enoates, spiro-3,4-dihydropyrans, (9S,9′′S)-9,9′′-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)] bis[10,11-dihydro-6′-methoxy-cinchonan], Dihydroquinidine Derivative

Spirocyclization

Spirocyclization, oxindoles, bromonitromethane, substituted tert-butyl (1R,2R,3S)-3-nitro-2′-oxospiro[cyclopropane-1,3′-indoline]-1′-carboxylate, N-[3,5-bis(trifluoromethyl)phenyl]-N′-[(9R)-10,11-dihydro-6′-methoxycinchonan-9-yl]-thiourea, Dihydroquinidine Derivative

Cyclopropanation, Spirocyclization

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