Organocatalytic and Enantioselective Mannich Reaction of Dicyanoolefins with α-Amido Sulfones.

DOI Number:

10.5012/bkcs.2012.33.10.3175

Reaction Category:

RXNO ID:

RXNO_0000032

Educt:

tert-butyl ((3-chlorophenyl)(phenylsulfonyl)methyl)carbamate, 2-(thiochroman-4-ylidene)malononitrile

Product:

tert-butyl ((S)-(3-chlorophenyl)((S)-4-(dicyanomethylene)thiochroman-3-yl)methyl)carbamate

Catalyst:

(8α,9R)-9-hydroxy-1-(phenylmethyl)-cinchonanium chloride

Cas No:

69257-04-1

Associated Product from Buchler GmbH:

N-Benzylcinchonidinium Chloride

Cas No:

69257-04-1