DOSY NMR for monitoring self aggregation of bifunctional organocatalysts: increasing enantioselectivity with decreasing catalyst concentration.

DOI Number:

10.1039/C0OB00047G

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

cyclohexenone, 2-methoxybenzenethiol

Product:

(S)-3-((2-methoxyphenyl)thio)cyclohexan-1-one

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7