Organocatalytic Asymmetric Fluorination/Semipinacol Rearrangement: An Efficient Approach to Chiral β‐Fluoroketones.

DOI Number:

10.1002/chem.201202444

Reaction Category:

MOP ID:

MOP_0000553

Educt:

substituted (3,4-dihydro-2H-pyran-6-yl)methanol, N-fluorobenzenesulfonimide

Product:

substituted 1-((2S,3S)-3-fluorotetrahydro-2H-pyran-2-yl)ethan-1-one

Catalyst:

(9S,9′′S)-9,9′′-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)]bis[10,11-dihydro-6′-methoxy-cinchonan]

Cas No:

149725-81-5

Cas No:

1435-55-8