A Copper Catalyst with a Cinchona‐Alkaloid‐Based Sulfonamide Ligand for Asymmetric Radical Oxytrifluoromethylation of Alkenyl Oximes.
DOI Number:
10.1002/anie.201804315
Reaction Category:
MOP ID:
MOP_0000368
Educt:
1,3-substituted but-3-enal oxime, 3,3-dimethyl-1-(trifluoromethyl)-1,3-dihydro-1l3-benzo[d][1,2]iodaoxole
Product:
cyclic alkenyl oximes
Catalyst:
copper acetate, N-[(9R)-10,11-dihydrocinchonan-9-yl]-2,3,4,5,6-pentamethyl-benzenesulfonamide
Cas No:
2228076-17-1
Associated Product from Buchler GmbH:
Dihydrocinchonine Base
Cas No:
485-65-4