Asymmetric Synthesis of Functionalized Tetrasubstituted α-Aminophosphonates through Enantioselective Aza-Henry Reaction of Phosphorylated Ketimines.
DOI Number:
10.1021/jo502233m
Reaction Category:
RXNO ID:
RXNO_0000235
Educt:
phosphorylated ketimines, nitromethane
Product:
tetrasubstituted alpha-aminophosphonates
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-(9S)-cinchonan-9-ylthiourea
Cas No:
851477-18-4
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5