Synthesis of Chiral Cyclic Nitrones by Asymmetric Addition of β‐Ketosulfones to Nitroalkenes followed by Reductive Cyclization.

DOI Number:

10.1002/chem.201001914

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

β‐ketosulfones, nitroalkenes

Product:

4-nitro-1,3-diphenyl-2-(phenylsulfonyl)butan-1-one

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7