Diastereodivergent Synthesis of α-chiral tertiary azides through catalytic asymmetric Michael addition.

DOI Number:

10.1021/acs.orglett.0c03178

Reaction Category:

Educt:

substituted 2-azido-2,3-dihydro-1H-inden-1-one, (E)-4-substituted-2-oxobut-3-enoate,

Product:

α-chiral tertiary azides

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-25-8

Cas No:

56-54-2