Molecular assembly of an achiral phosphine and a chiral primary amine: A highly efficient supramolecular catalyst for the enantioselective Michael reaction of aldehydes with maleimides.

DOI Number:

10.1002/asia.201300141

Reaction Category:

Educt:

N-aryl substituted maleimide, α-disubstituted aldehyde

Product:

N,C-substituted (R)-2-(2,5-dioxopyrrolidin-3-yl)acetaldehyde

Catalyst:

triphenylphosphane, (9R)-Cinchonan-9-amine

Cas No:

168960-96-1

Cas No:

118-10-5