Stereocontrolled Creation of Adjacent Quaternary and Tertiary Stereocenters by a Catalytic Conjugate Addition.

DOI Number:

10.1002/anie.200461923

Reaction Category:

Educt:

methyl 2-oxocyclopentane-1-carboxylate, (E)-(2-nitrovinyl)benzene

Product:

methyl (S)-1-((R)-2-nitro-1-phenylethyl)-2-oxocyclopentane-1-carboxylate

Catalyst:

(8α,9R)-9-(Phenylmethoxy) cinchonan-6′-ol

Cas No:

838821-39-9

Cas No:

524-63-0