Cinchona alkaloid-based chiral catalysts act as highly efficient multifunctional organocatalysts for the asymmetric conjugate addition of malonates to nitroolefins.
DOI Number:
10.1039/C5OB01351H
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
malonates, nitroolefins
Product:
substituted (R)-(1-nitropropan-2-yl)benzene
Catalyst:
(9S)-(9′′S)-1,1′′-[[2,2-bis[[4-[[(9S)-9-hydroxycinchonanium-1-yl]methyl]phenoxy]methyl]-1,3-propanediyl]bis(methyleneoxy-4,1-phenylenemethylene)]bis[9-hydroxy-cinchonanium bromide (1:4)
Cas No:
1821215-34-2
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5