Organocatalyzed Diastereo‐and Enantioselective Conjugate Addition of Nitroalkanes to β‐Silylmethylene Malonates: Direct Access to Enantioenriched Organosilanes.
DOI Number:
10.1002/ejoc.202000306
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
beta‐silylmethylene malonates, nitromethane
Product:
diethyl (R)-2-(1-(dimethyl(phenyl)silyl)-2-nitroethyl)malonate
Catalyst:
N-[(9R)-6′-methoxycinchonan-9-yl]-N′-(4-nitrophenyl)-Thiourea
Cas No:
2420498-38-8
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2