Diastereodivergent Synthesis of α-Chiral Tertiary Azides through Catalytic Asymmetric Michael Addition.

DOI Number:

10.1021/acs.orglett.0c03178
Link to literature

Reaction Category:

Michael | Michael Addition

RXNO ID:

RXNO_0000009

Educt:

alpha-azido indanones, beta,gamma-unsaturated alpha-ketoesters

Product:

alpha-chiral tertiary azides

Catalyst:

N-[(8α,9S)-10,11-dihydro-6′-hydroxycinchonan-9-yl]-Phosphoramidic acid diethyl ester

Cas No:

2545785-62-2

Associated Product from Buchler GmbH:

Dihydrocupreine Base

Cas No:

5962-19-6