Au (I)-Catalyzed Formal Intermolecular Carbene Insertion into Vinylic C (sp2)–H Bonds and Allylic C (sp3)–H Bonds.

DOI Number:

10.1021/acscatal.2c05351

Reaction Category:

Educt:

3-(2-phenylallyl)benzo[b]thiophen-2(3H)-one, (E)-(2-nitrovinyl)benzene

Product:

(S)-3-((R)-2-nitro-1-phenylethyl)-3-(2-phenylallyl)benzo[b]thiophen-2(3H)-one

Catalyst:

N-(8α,9S)-cinchonan-9-yl-phosphoramidic acid diethyl ester

Cas No:

2892388-91-7

Cas No:

485-71-2