Rationally designed amide donors for organocatalytic asymmetric Michael reactions.

DOI Number:

10.1002/ange.201200996

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

2-(4-nitrophenyl)-1-(1H-pyrazol-1-yl)ethan-1-one, (E)-1-(2-nitrovinyl)-2-(trifluoromethyl)benzene

Product:

(2R,3S)-4-nitro-2-(4-nitrophenyl)-1-(1H-pyrazol-1-yl)-3-(2-(trifluoromethyl)phenyl)butan-1-one

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-Urea

Cas No:

871334-33-7

Cas No:

522-66-7