Catalytic Enantioselective Synthesis of N, Cα, Cα‐Trisubstituted α‐Amino Acid Derivatives Using 1H‐Imidazol‐4(5H)‐ones as Key Templates.

DOI Number:

10.1002/anie.201501275

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

1H‐Imidazol‐4(5H)‐ones, 4-methyl-4-((trimethylsilyl)oxy)pent-1-en-3-one

Product:

substituted 5-(4-hydroxy-4-methyl-3-oxopentyl)-2-(alkylthio)-1,5-dihydro-4H-imidazol-4-one

Catalyst:

N-[3,5-bis(trifluoromethyl)phenyl]-3-[[2-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3,4-dioxo-1-cyclobuten-1-yl]amino]-benzamide

Cas No:

1807566-23-9

Cas No:

130-95-0