Highly enantioselective direct Michael addition of 1,3-dicarbonyl compounds to β-fluoroalkyl-α-nitroalkenes.

DOI Number:

10.1016/j.tet.2014.02.062
Link to literature

Reaction Category:

Michael | Michael Addition

RXNO ID:

RXNO_0000009

Educt:

1,3-dicarbonyl compounds, β-fluoroalkyl-α-nitroalkenes

Product:

substituted 2-(2-nitroethyl)-propane-1,3-dione

Catalyst:

(8α,9R)-Cinchonan-6′,9-diol-9-benzoate

Cas No:

876269-54-4

Associated Product from Buchler GmbH:

Cupreine Base

Cas No:

524-63-0