Control of diastereoselectivity in tandem asymmetric reactions generating nonadjacent stereocenters with bifunctional catalysis by cinchona alkaloids.

DOI Number:

10.1021/ja0670409

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

1-oxoindan-2-carbonitrile, 2-chloroacrylonitrile

Product:

(S)-2-((R)-2-chloro-2-cyanoethyl)-1-oxo-2,3-dihydro-1H-indene-2-carbonitrile

Catalyst:

Cupreidine Base

Cas No:

70877-75-7

Cas No:

70877-75-7