Organocatalytic Enantioselective γ-Position-Selective Mannich Reactions of β-Ketocarbonyl Derivatives.
DOI Number:
10.1021/acs.orglett.2c02433
Reaction Category:
RXNO ID:
RXNO_0000032
Educt:
6,8-dibromobenzo[e][1,2,3]oxathiazine 2,2-dioxide, β-Ketocarbonyls
Product:
ethyl (S)-4-(6,8-dibromo-2,2-dioxido-3,4-dihydrobenzo[e][1,2,3]oxathiazin-4-yl)-3-oxobutanoate
Catalyst:
(8α,9S)-6′-Methoxycinchonan-9-amine
Cas No:
168960-95-0
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0