β2, 2-Amino Acid N-Carboxyanhydrides Relying on Sequential Enantioselective C(4)-Functionalization of Pyrrolidin-2,3-diones and Regioselective Baeyer–Villiger Oxidation.
DOI Number:
10.1002/chem.201700464
Reaction Category:
Educt:
1,5-Dihydro-3-hydroxy-4-methyl-1-(1-naphthalenylmethyl)-2H-pyrrol-2-one, di-tert-butyl (E)-diazene-1,2-dicarboxylate
Product:
di-tert-butyl (R)-1-(3-methyl-1-(naphthalen-1-ylmethyl)-4,5-dioxopyrrolidin-3-yl)hydrazine-1,2-dicarboxylate
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-3-[[2-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3,4-dioxo-1-cyclobuten-1-yl]amino]-5-(trifluoromethyl)benzamide
Cas No:
2071700-89-3
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0