Catalytic Enantioconvergent Conjugate Addition of Organosilanes via a Strategy of Fluorodesilylation.
DOI Number:
10.1021/jacs.2c10777
Reaction Category:
MOP ID:
MOP_0000369
Educt:
organosilanes, alpha,beta unsaturated ketones
Product:
substituted (R,E)-5-(ethylideneamino)heptan-2-one
Catalyst:
Amberlyst A 26, (9S)-9-[(6-chloro-2,5-diphenyl-4-pyrimidinyl)oxy]-1-[[2′-(1,1-dimethylethoxy)[1,1′:3′,1′′-terphenyl]-5′-yl]methyl]-cinchonanium fluoride
Cas No:
2883123-51-9
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5