Cinchona Alkaloid Catalyzed Enantioselective Fluorination of Allyl Silanes, Silyl Enol Ethers, and Oxindoles.

DOI Number:

10.1002/ange.200800717

Reaction Category:

MOP ID:

MOP_0000553

Educt:

trimethyl((2-(4-methylbenzyl)-1H-inden-3-yl)methyl)silane, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide

Product:

(R)-2-fluoro-2-(4-methylbenzyl)-1-methylene-2,3-dihydro-1H-indene

Catalyst:

(8α,9R)-(8′′α,9′′R)-9,9′′-[(2,5-Diphenyl-4,6-pyrimidinediyl)bis(oxy)] bis[10,11-dihydro-6′-methoxycinchonan]

Cas No:

149820-65-5

Cas No:

522-66-7