One-pot fluorination and asymmetric Michael addition promoted by recyclable fluorous organocatalysts.
DOI Number:
10.1039/C3RA42501K
Reaction Category:
MOP ID:
MOP_0000553
Educt:
ethyl 3-oxo-3-phenylpropanoate, (E)-(2-nitrovinyl)benzene, selectfluor
Product:
ethyl (2S,3R)-2-benzoyl-2-fluoro-4-nitro-3-phenylbutanoate
Catalyst:
N-[(9R)-10,11-Dihydro-6′-methoxycinchonan-9-yl]-N′-[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]-thiourea
Cas No:
1456767-78-4
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8