Highly enantioselective epoxidation of α,β-unsaturated ketones using amide-based Cinchona Alkaloids as hybrid phase-transfer catalyst.

DOI Number:

10.1021/acs.orglett.0c03272
Link to literature

Reaction Category:

Epoxidation

MOP ID:

MOP_0000671

Educt:

alpha,beta-unsaturated ketones, hydrogen peroxide

Product:

chiral epoxides

Catalyst:

1-[2-([1,1′-biphenyl]-2-ylamino)-2-oxoethyl]-9-hydroxy-(8α,9R)-Cinchonanium bromide

Cas No:

2380293-72-9

Associated Product from Buchler GmbH:

Cinchonidine Base

Cas No:

485-71-2