The cinchona primary amine-catalyzed asymmetric epoxidation and hydroperoxidation of α, β-unsaturated carbonyl compounds with hydrogen peroxide.

DOI Number:

10.1021/ja402058v

Reaction Category:

MOP ID:

MOP_0000671

Educt:

alpha,beta-unsaturated carbonyl compounds, hydrogen peroxide

Product:

alpha,beta epoxy carbonyl compounds

Catalyst:

(8α,9S)-6′-methoxy-Cinchonan-9-amine-2,2,2-trifluoroacetate (1:2)

Cas No:

1228358-69-7

Cas No:

130-95-0