Tunable Cinchona‐Based Thioureas‐Catalysed Asymmetric Epoxidation to Synthetically Important Glycidic Ester Derivatives.

DOI Number:

10.1002/adsc.201700146

Reaction Category:

MOP ID:

MOP_0000671

Educt:

(E)-substituted methyl 2-cyanoacrylate, tert-butylhydroperoxid

Product:

(3R)-substituted methyl (2R)-2-cyanooxirane-2-carboxylate

Catalyst:

N-[(1R,2R)-2-amino-1,2-di-1-naphthalenylethyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]-thiourea

Cas No:

2088845-68-3

Cas No:

56-54-2