Enantioselective synthesis of epoxides having a tetrasubstituted trifluoromethylated carbon center: methylhydrazine-induced aerobic epoxidation of β,β-disubstituted enones.

DOI Number:

10.1002/anie.201209355

Reaction Category:

MOP ID:

MOP_0000671

Educt:

β-aryl-β-trifluoromethyl-disubstituted enones, oxygen

Product:

tetrasubstituted trifluoromethylated epoxides

Catalyst:

1-[[3,5-bis(trifluoromethyl)phenyl]methyl]-9-hydroxy-6′-methoxy-cinchonanium bromide

Cas No:

945732-76-3

Cas No:

56-54-2