Bifunctional Thiourea-Catalyzed Asymmetric Inverse-Electron-Demand Diels–Alder Reaction of Allyl Ketones and Vinyl 1,2-Diketones via Dienolate Intermediate.
DOI Number:
10.1021/acs.orglett.9b00035
Reaction Category:
RXNO ID:
RXNO_0000006
Educt:
allyl ketones, vinyl 1,2-diketones
Product:
substituted (3,4-dihydro-2H-pyran-6-yl)methanone
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-16-7
Associated Product from Buchler GmbH:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-16-7