Catalytic Enantioselective Construction of Decalin Derivatives by Dynamic Kinetic Desymmetrization of C2-Symmetric Derivatives through Aldol–Aldol Annulation.
DOI Number:
10.1021/acs.joc.2c00889
Reaction Category:
Educt:
symmetrical substituted 2,6-dioxoheptanedioate, 5-substituted cyclohexane-1,3-dione
Product:
decalin derivatives
Catalyst:
(9S)-10,11-Dihydro-6′-methoxy-9-(9-phenanthrenyloxy)cinchonan
Cas No:
135042-88-5
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8