A highly reactive and enantioselective bifunctional organocatalyst for the methanolytic desymmetrization of cyclic anhydrides: prevention of catalyst aggregation.

DOI Number:

10.1002/anie.200801636

Reaction Category:

Educt:

cyclic anhydrides, methanol

Product:

(1S,2R)-2-(methoxycarbonyl)cyclohexane-1-carboxylic acid

Catalyst:

N-[(8α,9S)-6′-Methoxycinchonan-9-yl]-3,5-bis(trifluoromethyl)benzenesulfonamide

Cas No:

1092116-26-1

Cas No:

130-95-0