Cu (I)-catalyzed chemo-and enantioselective desymmetrizing C–O bond coupling of acyl radicals.

DOI Number:

10.1021/jacs.3c00671

Reaction Category:

Educt:

aldehydes, 2,2-disubstituted propane-1,3-diol

Product:

substituted 3-hydroxypropylat

Catalyst:

(T-4)-[tetrahydroborato(1-)-κH,κH′]bis(triphenylphosphine)-copper, 2,4,6-trichloro-N-[(9R)-6′-methoxycinchonan-9-yl]-benzenesulfonamide

Cas No:

2917550-08-2

Cas No:

56-54-2