Elucidation of the active conformation of cinchona alkaloid catalyst and chemical mechanism of alcoholysis of meso anhydrides.
DOI Number:
10.1073/pnas.1004439107
Reaction Category:
Educt:
(3aR,7aS)-hexahydroisobenzofuran-1,3-dione, 2,2,2-trifluoroethan-1-ol
Product:
(1R,2S)-2-((2,2,2-trifluoroethoxy)carbonyl)cyclohexane-1-carboxylic acid
Catalyst:
2-[[(9S)-6′-methoxycinchonan-9-yl]oxy]-acetic acid (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester
Cas No:
811811-41-3
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2