Catalytic, enantio-and diastereoselective synthesis of γ-butyrolactones incorporating quaternary stereocentres.
DOI Number:
10.1039/C2CC32147E
Reaction Category:
MOP ID:
MOP_0000562
Educt:
substituted dihydrofuran-2,5-dione, aldehydes, trimethylsilyldiazomethane
Product:
2,3-disubstituted methyl 5-oxotetrahydrofuran-3-carboxylate
Catalyst:
3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxy-2′-phenylcinchonan-9-yl]amino]-3-cyclobutene-1,2-dione
Cas No:
1370022-11-9
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0