Organocatalytic asymmetric formal [3+2] cycloaddition as a versatile platform to access methanobenzo [7] annulenes.

DOI Number:

10.1002/anie.201706557

Reaction Category:

MOP ID:

MOP_0000715

Educt:

1-substituted prop-2-en-1-one, substituted 2-hydroxynaphthalene-1,4-dione

Product:

methanobenzo[7]annulenes

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7