Enantioconvergent 6π electrocyclization enabled by photoredox racemization.

DOI Number:

10.1021/jacs.3c06227
Link to literature

Reaction Category:

Cyclization | Further Cyclizations | Intramolecular cyclization

MOP ID:

MOP_0000561

Educt:

methyl (E)-2-(((2-hydroxyphenyl)(phenyl)methylene)amino)-2-(4-(trifluoromethyl)phenyl)acetate

Product:

methyl (S)-4-phenyl-2-(4-(trifluoromethyl)benzyl)-2H-benzo[e][1,3]oxazine-2-carboxylate

Catalyst:

cobalt(II) tetrafluoroborate, 2-((E)-(((S)-((1S,2S,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methyl)imino)methyl)phenol

Cas No:

Associated Product from Buchler GmbH:

Dihydroquinine Base

Cas No:

522-66-7